Phase behavior of a confined nanodroplet in the grand-canonical ensemble: the reverse liquid–vapor transition

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Phase behavior of a confined nanodroplet in the grand-canonical ensemble: the reverse liquid-vapor transition.

The equilibrium density distribution and thermodynamic properties of a Lennard-Jones fluid confined to nanosized spherical cavities at a constant chemical potential was determined using Monte Carlo simulations. The results describe both a single cavity with semi-permeable walls as well as a collection of closed cavities formed at the constant chemical potential. The results are compared to calc...

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N ov 2 00 9 Phase behavior of a confined nano - droplet in the grand - canonical ensemble : the reverse liquid - vapor transition

The equilibrium density distribution and thermodynamic properties of a Lennard-Jones fluid confined to nano-sized spherical cavities at constant chemical potential was determined using Monte Carlo simulations. The results describe both a single cavity with semipermeable walls as well as a collection of closed cavities formed at constant chemical potential. The results are compared to calculatio...

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ژورنال

عنوان ژورنال: Journal of Physics: Condensed Matter

سال: 2009

ISSN: 0953-8984,1361-648X

DOI: 10.1088/0953-8984/22/3/035101